Start by introducing some variables. For example, let a be the current number of students in Van A and b be the current number of students in Van B. If you want to find the value of the 2 variables, then you need 2 equations.
Consider the first statement:
"If 2 students move from van A to van B, then the two vans would have the same amount of students in each".
In terms of "a", how many students are now in van A? In terms of "b", how many students are now in van B? What does "have the same amount of students in each" tell you about these two expressions? This will give you one equation.
Now consider the second statement and break it down in a similar way to get a second equation.
Can you proceed? Please show us what you have done.