Stirling's approximation is:
\(\displaystyle n!\sim n^{n}e^{-n}\sqrt{2\pi n}\)
But, this would actually involve the Psi function, not Stirling. I suppose it could be done with Stirling, but there is a function which defines the derivative of logs and factorials. It's called the Psi or Digamma function.
The Psi function is defined as the derivative of the Log Gamma function. Thus,
\(\displaystyle \psi(n)=\frac{d}{dn}ln\Gamma(n)=\frac{\Gamma'(n)}{\Gamma(n)}\)
So, if we have \(\displaystyle ln\left(\frac{n!}{s!(n-s)!}\right)\) and noting that \(\displaystyle n!=\Gamma(n+1)\), then differentiating in terms of s gives:
\(\displaystyle ln(\frac{n!}{(n-s)!s!})=ln(n!)-ln((n-s)!)-ln(s!)\)
\(\displaystyle =ln(\Gamma(n+1))-ln(\Gamma(n-s+1))-ln(\Gamma(s+1))\)
\(\displaystyle \frac{d}{ds}\left[ln(\Gamma(n+1))-ln(\Gamma(n-s+1))-ln(\Gamma(s+1))\right]\)
\(\displaystyle =\psi(n-s+1)-\psi(s+1)\).