Obviously the answer to the question is yes - The series does converge or diverge.
Looking at the series, we note that the series obviously converges for x1 = 0 [xn = 0 for all n] and for x1=\(\displaystyle \pi\) [xn = \(\displaystyle \pi\) for all n]. Thus we need only consider the interval (0,\(\displaystyle \pi\)).
Consider the sequence
xn+1= xn-sin(xn)
or
0 < sin(xn) = xn - xn+1
on (0,\(\displaystyle \pi\))
Thus xn is a decreasing sequence on (0,\(\displaystyle \pi\)). Let
f(x) = x - sin(x)
then
f'(x) = 1 - cos(x)
and
f''(x) = sin(x).
Since cos(x) \(\displaystyle \le\) 1 and sin(x) is non negative on [0,\(\displaystyle \pi\)], f(x) is non-decreasing on [0,\(\displaystyle \pi\)]. Thus the minimum of x - sin(x) occurs at the endpoint 0. That is the minimum of x-sin(x) on [0,\(\displaystyle \pi\)] is zero. Thus the sequence is bounded below.
Since a decreasing sequence bounded below converges, xn+1= xn-sin(xn) converges.
EDIT: Since, if xn converges, xn+j converges to the same thing for any finite fixed j, if xn converges to x we must have
x = x - sin(x)
or, with x confined to [0,pi], x=0 or x=pi.