One complicating factor is that each expert is not just guessing randomly; they are using some data to make their predictions. Moreover, their predictions probably are not independent. So I'm not sure probability even applies here. But a Bayesian approach may be appropriate.
I disagree with Romsek's statement that "We aren't given the probability that the experts correctly predict A losing." We are given that each has "an 80% success rate of guessing the right team to win", and if they guess that a given team will win, they are at the same time predicting that the other team loses.
I'm going to change the question to one about an area I'm more familiar with. Suppose that Romsek and I both solve a math problem. Each of us has an 80% success rate in getting the math right; that means 20% of the time we make at least one mistake. Now we both solve the same problem, and we get the same answer, say 17. How likely is it that we are right? [This is different from the question asked, because there are many possible wrong answers, rather than just a choice between A and B.]
Suppose that 17 is the wrong answer. Then both of us made mistakes. That happens 0.20*0.20 = 0.04 of the time.
Suppose that 17 is the right answer. Then both of us were right. That happens 0.80*0.80 = 0.64 of the time.
Those are the only two possibilities (ignoring the fact that we might also get the right answer by incorrect work ...), so the probability that what happened would happen is 0.04 + 0.64 = 0.68. Therefore the probability that 17 is the right answer is 0.64/0.68 = 0.94.
Does that sound better? I'm not entirely convinced, but I think it's the best answer I've found.