1) Notice that men and women are not considered together on this chart. The rows for women all add to 100% The rows for men all add to 100%. The columns all add to 100%. It is important to observe the structure so we can have a clue what kind of information exists. In particular, we CANNOT answer, "What is the proportion of men in the population?" Unless we know the relative sizes of the male population and female population, we can't answer that question.
2) Likewise, we cannot tell the proportion of unmarried men vs. married men for the entire population (or women). Again, without the relative sizes of the population in the two groups, the question remains a mystery.
3) Read the question VERY CAREFULLY. It asks only about a single column from the table. Which one?
4) Answer the question.